The Mathematical Modeling for CoO(OH) – Poly(5-Amino-1,4-Naphthoquinone) Composite-Based Sensor for 1-Propenesulfenic Acid and Propanethial S-Oxide Detection in Food and Lacrimogenic Compositions
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The Mathematical Modeling for CoO(OH) – Poly(5-Amino-1,4-Naphthoquinone) Composite-Based Sensor for 1-Propenesulfenic Acid and Propanethial S-Oxide Detection in Food and Lacrimogenic Compositions
Tkach, Volodymyr V.; Kushnir, Marta V.; Kopiika, Vira V.; Yeshchenko, Yuliia V.; Luganska, Olga V.; Kormosh, Zholt O.; Nazymok, Yevgeniya V.; Ivanushko, Yana G.; Molodianu, Anzhelika F.; Ostapchuk, Valentyna G.; Melnychuk, Svitlana P.; Blazheyevskiy, Mykola Ye.; Palamarek, Karina V.; Fedorova, Dina V.; De Oliveira, Sílvio C.; Yagodynets, Petro I.; Da Silva, Adriano O.
Abstract: The theoretical description for 1-propenesulfenic acid and its isomer propanethial-S-oxide, substances, responsible for leek lacrimogenic activity, has been described theoretically. The process is realized anodically over a poly(naphthoquinone) – CoO(OH) composite. A model has been developed and analyzed using linear stability theory and bifurcation analysis. According to the model analysis, the ionic compound's transformation during the sulfenic acid oxidation may be responsible for the oscillatory and monotonic instability alongside the double electric layer (DEL) influences of the electrochemical stage. Nevertheless, the model's analysis shows that the electroanalytical process is efficient for determining both of the analytes.